Emerging contaminants in ecosystems : new challenges for water reuse implementation and mechanisms of perfluorochemical bioaccumulation

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Abstract/Contents

Abstract
Technological innovations developed in response to pressing water supply needs in populated arid regions have led to the recovery of municipal wastewater for beneficial reuse worldwide. Yet even as rapid urbanization and severe droughts motivate wastewater reuse, new engineering and policy hurdles arise over public concerns and management challenges regarding the persistence of residual and byproduct pharmaceutical and industrial chemicals in treated municipal effluent. Bioaccumulation of synthetic organic chemicals in environments downstream of wastewater effluent discharge and recycled water use poses an ecological risk and introduces a potential pathway of human exposure to these contaminants. This dissertation assesses management challenges for water reuse implementation in Northern California; identifies opportunities of water reuse for ecosystem enhancement; explores the bioaccumulation of one class of persistent and toxic unregulated chemical contaminants, perfluoroalkyl acids (PFAAs); and evaluates mechanisms of bioaccumulation via an in-depth study of PFAA interactions with a model serum protein. This study provides context for issues surrounding chemicals of emerging concern (CECs) in recycled water. However, uncertainty regarding bioaccumulation of CECs from recycled water used for ecological enhancement or habitat creation remains a concern. Investigation of mechanisms influencing PFAA bioaccumulation provides insight into one class of CECs now detected in sensitive aquatic ecosystems and contributes to ongoing efforts to characterize the physiochemical properties of compounds used to replace long-chain perfluorinated chemicals.

Description

Type of resource text
Form electronic; electronic resource; remote
Extent 1 online resource.
Publication date 2011
Issuance monographic
Language English

Creators/Contributors

Associated with Bischel, Heather Nicole
Associated with Stanford University, Civil & Environmental Engineering Department
Primary advisor Luthy, Richard G
Thesis advisor Luthy, Richard G
Thesis advisor MacManus-Spencer, Laura (Laura Ann)
Thesis advisor Reinhard, Martin
Advisor MacManus-Spencer, Laura (Laura Ann)
Advisor Reinhard, Martin

Subjects

Genre Theses

Bibliographic information

Statement of responsibility Heather Nicole Bischel.
Note Submitted to the Department of Civil and Environmental Engineering.
Thesis Thesis (Ph.D.)--Stanford University, 2011.
Location electronic resource

Access conditions

Copyright
© 2011 by Heather Nicole Bischel
License
This work is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported license (CC BY-NC).

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