Developing gold-based electrocatalysts for the production of fuels from CO2 and water

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Abstract/Contents

Abstract
Carbon dioxide electroreduction is presented as a way to convert CO2 into commodity chemicals. This thesis starts with an overview of CO2 electroreduction, the methods used to study CO2 electroreduction catalysts and analysis of a specific application of CO2RR: the conversion of CO2 emissions from the fermentation of corn. Subsequently, a thorough analysis of gold as a catalyst for CO2 electroreduction is presented, followed by analysis of four novel gold-based materials for CO2 electroreduction. For these materials, electrochemical analysis and characterization is discussed as well as some mechanistic implications. The thesis is concluded with a combination of theory and experimental hydrogen partial current densities to generate a relationship between surface CO-binding and HER during CO2 electroreduction.

Description

Type of resource text
Form electronic; electronic resource; remote
Extent 1 online resource.
Publication date 2015
Issuance monographic
Language English

Creators/Contributors

Associated with Cave, Etosha
Associated with Stanford University, Department of Mechanical Engineering.
Primary advisor Jaramillo, Thomas Francisco
Primary advisor Mitchell, Reginald
Thesis advisor Jaramillo, Thomas Francisco
Thesis advisor Mitchell, Reginald
Thesis advisor Nørskov, Jens K
Advisor Nørskov, Jens K

Subjects

Genre Theses

Bibliographic information

Statement of responsibility Etosha Cave.
Note Submitted to the Department of Mechanical Engineering.
Thesis Thesis (Ph.D.)--Stanford University, 2015.
Location electronic resource

Access conditions

Copyright
© 2015 by Etosha Cave

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