Spectroscopic and theoretical studies of copper-oxygen intermediates in enzyme model complexes and zeolites : electronic structure contributions to reactivity
Abstract/Contents
- Abstract
- Copper-oxygen species catalyze a wide range of biologically and catalytically relevant reactions. In this dissertation a combined spectroscopic and theoretical approach is used to define the geometric and electronic structure of two copper-oxygen intermediates proposed to be activated for H-atom abstraction: an end-on bound mononuclear cupric-superoxo and a zeolitic site activated for methane monooxygenation.
Description
| Type of resource | text |
|---|---|
| Form | electronic; electronic resource; remote |
| Extent | 1 online resource. |
| Publication date | 2010 |
| Issuance | monographic |
| Language | English |
Creators/Contributors
| Associated with | Woertink, Julia Salas |
|---|---|
| Associated with | Stanford University, Department of Chemistry |
| Primary advisor | Solomon, Edward I |
| Thesis advisor | Solomon, Edward I |
| Thesis advisor | Hodgson, K. O. (Keith O.), 1947- |
| Thesis advisor | Stack, T. (T. Daniel P.), 1959- |
| Advisor | Hodgson, K. O. (Keith O.), 1947- |
| Advisor | Stack, T. (T. Daniel P.), 1959- |
Subjects
| Genre | Theses |
|---|
Bibliographic information
| Statement of responsibility | Julia Salas Woertink. |
|---|---|
| Note | Submitted to the Department of Chemistry. |
| Thesis | Ph.D. Stanford University 2010 |
| Location | electronic resource |
Access conditions
- Copyright
- © 2010 by Julia Salas Woertink
- License
- This work is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported license (CC BY-NC).
Also listed in
Loading usage metrics...