The Significance of CO2 Solubility in Deep Subsurface Environments

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Abstract/Contents

Abstract
This paper considers the idea of CO2 injection into the subsurface with the goal of sequestering carbon dioxide. This may occur in a couple of ways: in the traditional sense, carbon capture and sequestration would involve direct injection into the ground with the goal of sequestering as much as possible. In addition, the concept of CO2 sequestration has been modified in within the past ten years to consider circulating CO2 through the subsurface in order to simultaneously produce heat and sequester CO2 via fluid loss. To use current terminology, the carbon dioxide would be used as the working fluid in an Engineered Geothermal Systems (EGS). This scenario would have the two-fold advantage of providing renewable electricity generation with simultaneous CO2 sequestration via subsurface fluid loss. In order to entertain this idea seriously, it is necessary to consider the interactions between CO2 and the reservoir rock and connate fluid. Laboratory experiments and theoretical work were designed to investigate thermodynamic effects that may occur when solubility is taken into account. A core-scale experiment measured relative permeabilities in the two-phase system, a micromodel experiment qualitatively observed the dynamic dissolution phenomenon, and theoretical analyses put the findings in context and provided a framework to predict results under varied conditions. The purpose of this research was to analyze and quantify the magnitude of dissolution effects through laboratory and theoretical work. An additional goal was to evaluate the time and length-scales of dissolution and diffusion effects relative to standard hydrodynamic behavior.

Description

Type of resource text
Date created June 2011

Creators/Contributors

Author Pistone, Sarah
Primary advisor Horne, Roland N.
Degree granting institution Stanford University, Department of Energy Resources Engineering

Subjects

Subject School of Earth Energy & Environmental Sciences
Genre Thesis

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User agrees that, where applicable, content will not be used to identify or to otherwise infringe the privacy or confidentiality rights of individuals. Content distributed via the Stanford Digital Repository may be subject to additional license and use restrictions applied by the depositor.

Preferred citation

Preferred Citation
Pistone, Sarah. (2011). The Significance of CO2 Solubility in Deep Subsurface Environments. Stanford Digital Repository. Available at: https://purl.stanford.edu/rh712qk7553

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Master's Theses, Doerr School of Sustainability

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