Two-step laser mass spectrometric investigations of terrestrial and extraterrestrial samples

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Abstract/Contents

Abstract
The studies detailed in this thesis center around the application of laser mass spectrometry to a variety of terrestrial and extraterrestrial samples and their polycyclic aromatic hydrocarbon (PAH) contents. Though PAHs are ubiquitous in space, on Earth and, indeed, in our everyday lives, determination of characteristic PAH signatures in samples of interest can provide important clues to the mechanisms of asteroid interactions, answer questions about experimental contamination, and even help to decipher the riddles of extraterrestrial life. Specifically, this thesis describes the use of two-step laser desorption laser ionization mass spectrometry (L2MS) to: (i) determine that photochemical reactions are not a source of contaminating aromatics in NASA's Stardust mission; (ii) confirm that meteorites collected in the area of a witnessed near-Earth object (NEO) impact were indeed part of the parent asteroid; (iii) contribute to the on-going question of biotic or abiotic formation of carbonate/magnetite globules in mineralogical formations; and (iv) show that L2MS is a promising alternative to laser desorption/ionization mass spectrometry (LDI-MS) for analytes prone to gas-phase aggregation.

Description

Type of resource text
Form electronic; electronic resource; remote
Extent 1 online resource.
Publication date 2012
Issuance monographic
Language English

Creators/Contributors

Associated with Morrow, Amy Louise
Associated with Stanford University, Department of Chemistry
Primary advisor Zare, Richard N
Thesis advisor Zare, Richard N
Thesis advisor Andersen, Hans, 1941-
Thesis advisor Boxer, Steven G. (Steven George), 1947-
Advisor Andersen, Hans, 1941-
Advisor Boxer, Steven G. (Steven George), 1947-

Subjects

Genre Theses

Bibliographic information

Statement of responsibility Amy Louise Morrow.
Note Submitted to the Department of Chemistry.
Thesis Ph.D. Stanford University 2012
Location electronic resource

Access conditions

Copyright
© 2012 by Amy Louise Morrow
License
This work is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported license (CC BY-NC).

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