Decomposition kinetics of the rocket propellant RP-1 and its chemical kinetic surrogates

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Abstract/Contents

Abstract
High-temperature fuel decomposition is an important aspect of fuel chemistry, and a thorough understanding of this process is necessary in order to accurately describe combustion chemistry. Two major motivations drive the study of kerosene decomposition. First, it is a vital building block upon which oxidation chemistry can be built, and second, it is used as a coolant in many rockets and high-speed aircraft. Measurements of fuel and ethylene time histories during decomposition of RP-fuels and their possible surrogate components were carried out between 1000 and 1500 K in two shock tubes. From these measurements, overall fuel decomposition rates for six fuels (RP-1, RP-2, JP-7, n-dodecane, methylcyclohexane, and iso-cetane) were determined and ethylene yields for four of these fuels (RP-1, n-dodecane, methylcyclohexane, and iso-cetane) were also determined. An RP-1 decomposition surrogate was formulated based on three targets: compound class, overall fuel decomposition rate, and ethylene yield. This resulted in a surrogate containing 32% n-dodecane, 59% methylcyclohexane, and 9% iso-cetane.

Description

Type of resource text
Form electronic; electronic resource; remote
Extent 1 online resource.
Publication date 2012
Issuance monographic
Language English

Creators/Contributors

Associated with MacDonald, Megan Edwards
Associated with Stanford University, Department of Mechanical Engineering
Primary advisor Hanson, Ronald
Thesis advisor Hanson, Ronald
Thesis advisor Bowman, Craig T. (Craig Thomas), 1939-
Thesis advisor Mitchell, Reginald
Advisor Bowman, Craig T. (Craig Thomas), 1939-
Advisor Mitchell, Reginald

Subjects

Genre Theses

Bibliographic information

Statement of responsibility Megan Edwards MacDonald.
Note Submitted to the Department of Mechanical Engineering.
Thesis Ph.D. Stanford University 2012
Location electronic resource

Access conditions

Copyright
© 2012 by Megan Edwards MacDonald
License
This work is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported license (CC BY-NC).

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