Useful thermal effects in electrochemical systems

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Abstract/Contents

Abstract
Redox reactions with high entropy changes can be used to make effective refrigerators and heat engines. This work demonstrates electrochemical systems that harvest heat energy (with efficiency > 60% of Carnot) and can provide effective cooling (at power > 0.5W/cm^3). A key advantage is that electromigration and mass advection in electrolytes can be optimized separately to decouple charge, entropy, and heat transport in ways that aren't possible with solid-state thermoelectrics. While these devices are a long way from any practical use, they might inform or inspire other researchers working towards hydrofluorocarbon-free refrigeration or energy harvesting.

Description

Type of resource text
Form electronic resource; remote; computer; online resource
Extent 1 online resource.
Place California
Place [Stanford, California]
Publisher [Stanford University]
Copyright date 2019; ©2019
Publication date 2019; 2019
Issuance monographic
Language English

Creators/Contributors

Author McKay, Ian Salmon
Degree supervisor Cargnello, Matteo
Degree supervisor Majumdar, Arunava
Thesis advisor Cargnello, Matteo
Thesis advisor Majumdar, Arunava
Thesis advisor Chueh, William
Degree committee member Chueh, William
Associated with Stanford University, Department of Chemical Engineering.

Subjects

Genre Theses
Genre Text

Bibliographic information

Statement of responsibility Ian Salmon McKay.
Note Submitted to the Department of Chemical Engineering.
Thesis Thesis Ph.D. Stanford University 2019.
Location electronic resource

Access conditions

Copyright
© 2019 by Ian Salmon McKay
License
This work is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported license (CC BY-NC).

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