Nanostructures in III-V solar cells

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Abstract/Contents

Abstract
From the physics and materials viewpoint, III-V materials are ideal for highly efficient photovoltaic conversion. Their major limitations are cost and resource availability. As industrial planar III-V solar cells continue to set the all-time efficiency records, nanostructured III-V solar cells are now being investigated in academia with the goal to further improve the efficiency and lower the required materials volume and cost. However, most previously investigated nano-structured solar cells suffer from low efficiencies. In this dissertation, I first present optical enhancement in nanopyramid III-V ultra-thin films which can potentially reduce the required materials by one order of magnitude. I then demonstrate significant efficiency improvement in GaAs solar cell. Especially, with an AlGaAs nanocone window layer, a 17%-efficiency nanostructured single-junction solar cell is obtained. The first part of my dissertation focuses on optical engineering and absorption improvement in nanopyramid GaAs ultra-thin film. I demonstrate a double-sided nanopyramid GaAs film that is only 160 nm thick, laminated in a flexible transparent superstrate. Without additional antireflection coatings, this nanopyramid film absorbs over 80% more photons than a planar counterpart with equal thickness at normal incidence and is equivalent to a 1um thick film. At large incident angles, this enhancement can be even greater. With similar light trapping design, III-V solar cell film thickness can be potentially reduced from 3-4 um to 200-300 nm, which could significantly reduce III-V cell cost. The second part of my dissertation focuses on efficiency improvement in III-V nanostructured solar cells. First, GaAs solar cell efficiency enhancement using ZnO nanoparticle antireflection coating is briefly demonstrated. I then demonstrate our work on nanostructured p-n junction solar cells and discuss the challenges for nanostructured solar cell. After this, I propose a nanowindow solar cell design that can overcome these challenges by enhancing both optical and electrical properties. A nanowindow solar cell using a nanocone AlGaAs window layer, a GaAs junction and mesa grid contact is demonstrated with a high energy conversion efficiency of 17.0% and high open circuit voltage of 0.982 V.

Description

Type of resource text
Form electronic; electronic resource; remote
Extent 1 online resource.
Publication date 2013
Issuance monographic
Language English

Creators/Contributors

Associated with Liang, Dong
Associated with Stanford University, Department of Physics.
Primary advisor Harris, J. S. (James Stewart), 1942-
Thesis advisor Harris, J. S. (James Stewart), 1942-
Thesis advisor Cui, Yi, 1976-
Thesis advisor Fan, Shanhui, 1972-
Thesis advisor Hollberg, Leo (Leo William)
Advisor Cui, Yi, 1976-
Advisor Fan, Shanhui, 1972-
Advisor Hollberg, Leo (Leo William)

Subjects

Genre Theses

Bibliographic information

Statement of responsibility Dong Liang.
Note Submitted to the Department of Physics.
Thesis Thesis (Ph.D.)--Stanford University, 2013.
Location electronic resource

Access conditions

Copyright
© 2013 by Dong Liang
License
This work is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported license (CC BY-NC).

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