Development of novel methods for the formation of C-C and C-N bonds
Abstract/Contents
- Abstract
- Carbon-carbon and carbon-nitrogen bonds are some of the most common motifs in organic molecules and as a result, the invention of new methods for selectively forming these bonds is highly important. The first half of this thesis describes the discovery of two novel and unexpected carbon-carbon bond forming reactions, and also includes a review on the unique chemistry of geminal and vicinal bis(sulfones). The second half of this work deals with enantioselective carbon-nitrogen bond formation, and describes the development of two transition metal-catalyzed asymmetric allylic alkylation reactions. It also contains a review on annulative allylic alkylation reactions between dual electrophiles and dual nucleophiles and their applications in complex molecule synthesis.
Description
Type of resource | text |
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Form | electronic resource; remote; computer; online resource |
Extent | 1 online resource. |
Place | California |
Place | [Stanford, California] |
Publisher | [Stanford University] |
Copyright date | 2019; ©2019 |
Publication date | 2019; 2019 |
Issuance | monographic |
Language | English |
Creators/Contributors
Author | Kalnmals, Christopher Andre | |
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Degree supervisor | Trost, Barry M | |
Thesis advisor | Trost, Barry M | |
Thesis advisor | Burns, Noah | |
Thesis advisor | Kanan, Matthew William, 1978- | |
Degree committee member | Burns, Noah | |
Degree committee member | Kanan, Matthew William, 1978- | |
Associated with | Stanford University, Department of Chemistry. |
Subjects
Genre | Theses |
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Genre | Text |
Bibliographic information
Statement of responsibility | Christopher A. Kalnmals. |
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Note | Submitted to the Department of Chemistry. |
Thesis | Thesis Ph.D. Stanford University 2019. |
Location | electronic resource |
Access conditions
- Copyright
- © 2019 by Christopher Andre Kalnmals
- License
- This work is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported license (CC BY-NC).
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